The safest Mordants and Assists
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The safest Mordants and Assists

GOTS vs. FDA What’s the Difference and Why It Matters

GOTS stands for the Global Organic Textile Standard, the leading worldwide certification for organic fibers. It regulates the entire textile supply chain from field to finished fabric and it focuses on environmental impact, worker safety, and chemical safety. Only substances on its Positive List may be used, and inputs must be biodegradable, non-toxic, and safe for ecosystems.

FDA-approved means that a substance is considered safe for use in food or cosmetics by the U.S. Food and Drug Administration. This applies to human ingestion or topical use and includes substances like alum, cream of tartar, and citric acid.

While FDA approval focuses on personal safety, especially in products we eat or put on our skin, GOTS approval focuses on the safety of the entire process from raw material to wastewater with minimal harm to people and the planet.

Natural dyers who care about ecological integrity, and non-toxic processes, or who work with organic-certified fibers, need to check both lists. A substance might be food-safe (FDA) but not permitted under GOTS, like stannous chloride. At the same time, many GOTS-approved assists are also used in food or skincare, making them safe, gentle, and earth-friendly choices.

GRAS-Approved / Food-Grade Mordants & Dye Auxiliaries

These substances are approved by the U.S. FDA (and often also by EFSA) for use in food, and some also in cosmetics. Their approval under GRAS (Generally Recognized As Safe) makes them great choices for non-toxic natural dyeing.

Alum (Potassium Aluminum Sulfate, KAl(SO₄)₂·12H₂O)

FDA status: GRAS – 21 CFR § 182.1125

Uses:

Food: As a firming agent in pickles and as a component of baking powder.
In the kitchen, alum appears quietly but effectively, strengthening the structure of foods that would otherwise soften, lending crispness to pickles and stability to certain baking preparations.

Cosmetics: Common in natural deodorants, styptic pencils, and astringents.
Applied to the body, it functions through its tightening and antibacterial qualities, making it a long-standing ingredient in simple, utilitarian formulations concerned with control and cleanliness rather than embellishment.

Dyeing: The primary mordant for bright, lightfast results. Safe and traditional.
Within the dye bath, alum is foundational: it binds color to fiber with reliability, producing clear, stable hues while maintaining the integrity of the material, and has remained central to textile dyeing practices for centuries.

Note: Food-grade alum is readily available.
Its accessibility in food-grade form reflects its broad acceptance across disciplines, allowing it to move seamlessly between kitchen, body, and workshop.


Stannous Chloride (Tin(II) Chloride, SnCl₂)

FDA status: GRAS – 21 CFR § 182.99

Uses:

Food: Preserves color in canned white potatoes and mushrooms.
In food processing, it serves a highly specific role: preventing discoloration and maintaining the visual clarity of pale ingredients that would otherwise dull during preservation.

Dyeing: Yields vibrant reds with cochineal and unique tones with flavonoids.
In dyeing, its effect is far more expressive, intensifying reds to a striking brilliance and shifting plant-based yellows into unexpected, luminous variations, though always with a degree of caution due to its strength.


Cream of Tartar (Potassium Bitartrate, KHC₄H₄O₆)

FDA status: GRAS – 21 CFR § 184.1077

Uses:

Food: Stabilizer in baking, especially in meringues and candies.
In culinary practice, it acts as a quiet stabilizer, supporting delicate structures such as whipped egg whites and sugar work, where control over texture is essential.

Dyeing: Adjusts pH and improves alum mordanting, especially on protein fibers.
In the dye bath, it refines rather than transforms, softening conditions and assisting alum in achieving more even, often warmer results on fibers such as wool and silk.


Citric Acid

FDA status: GRAS – 21 CFR § 184.1033

Uses:

Food: Common acidulant in beverages, preserves, and candies.
Its sharp, clean acidity defines it as a fundamental balancing agent in food, brightening flavors and stabilizing formulations across a wide range of applications.

Cosmetics: Found in bath bombs, facial products, and shampoos.
In cosmetic formulations, it contributes both to sensory experience and chemical balance, regulating pH while enhancing the feel and performance of the product.

Dyeing: pH adjustment, pre-treatment for cellulose.
In textile work, it operates as a precise tool, gently lowering pH to prepare fibers or influence color development without introducing additional complexity.


Tartaric Acid

FDA status: GRAS – 21 CFR § 184.1097

Uses:

Food: Found in grapes; used in baking powder and candies.
Naturally present in grapes, it carries with it a long history of culinary use, where it contributes both acidity and structure in confections and baked goods.

Dyeing: Less common but can help adjust pH for certain recipes.
In dyeing, it appears more rarely, yet offers a subtle means of adjusting conditions when a softer or more specific acidic environment is required.


Sodium Bicarbonate (Baking Soda, NaHCO₃)

FDA status: GRAS – 21 CFR § 184.1736

Uses:

Food: Baking, pH control, leavening.
In the kitchen, it is both reactive and structural, releasing gas to create lift while also moderating acidity within a recipe.

Dyeing: pH raiser for indigo vats and color shifting.
In the dye studio, it gently raises alkalinity, supporting processes such as indigo reduction and enabling controlled shifts in color through pH manipulation.


Sodium Carbonate (Soda Ash, Na₂CO₃)

FDA status: GRAS – 21 CFR § 184.1742

Uses:

Food: Used in pretzels (gives “lye” taste), and ramen noodles.
Its role in food is defined by transformation: altering texture and flavor, creating the distinctive chew of noodles or the characteristic crust of pretzels.

Dyeing: Crucial for hydros indigo vats, and scouring cellulose.
In dyeing, it is a strong and decisive agent, establishing the alkaline conditions required for indigo vats and effectively cleaning plant fibers in preparation for dye.


Calcium Hydroxide (Slaked Lime / Pickling Lime)

FDA status: GRAS – 21 CFR § 184.1205

Uses:

Food: In nixtamalization (corn for tortillas), pickling.
Its culinary significance is deeply rooted in tradition, transforming corn through nixtamalization and contributing to the preservation and texture of pickled foods.

Dyeing: Alkali for indigo vats (alternative to soda ash or caustic soda).
In dyeing, it provides a stable alkaline environment, often preferred in traditional indigo systems where a slower, more controlled development of the vat is desired.

Not GRAS, But Common in Dyeing (Use with Caution)

These substances do not have GRAS status and should not be used in food or cosmetics, but are common in traditional and modern dye practices:

Substance Status Notes
Ferrous Sulfate ❌ Not GRAS Toxic in excess; used in iron mordanting
Copper Sulfate ❌ Not GRAS Toxic; banned in eco-label dye processes
Aluminum Acetate ⚠️ Not GRAS Used in dermatology (Burow’s solution); not approved for food
Aluminum Triformate ⚠️ Not GRAS Eco-friendly mordant, no current FDA status
Tannins (e.g. Oak Gall, Myrobalan) ✅ Safe but not regulated as additives Naturally occurring plant substances, used in food (e.g. teas) but not isolated as food additives
Calcium Carbonate (chalk) ✅ Used in food and dyeing Used to neutralize pH or modify shades

What This Means for Natural Dyeing

If you're committed to safe, earth-friendly, and non-toxic processes, you can confidently use alum, cream of tartar, citric acid, stannous chloride, soda ash, and baking soda, knowing they're all food-grade and GRAS-approved. These substances are ideal for home dyeing, sensitive users, and even dyeing products for babies or therapeutic uses, assuming proper rinsing and safe handling. Mordants like iron or copper sulfate are useful but should be approached with care due to their toxicity and environmental impact. The ferrous sulfate, having such a bad reputation, came as a shock to me, I tell you!

GOTS-Approved Mordants and Assists

The Global Organic Textile Standard (GOTS) is the leading certification for organic textiles. It restricts inputs based on human safety, environmental impact, and biodegradability. Only permitted substances from the GOTS Positive List may be used in certified processing. The mordant itself does not require a GOTS certificate to qualify for GOTS certification of your finished textile. By the way: do not count on GOTS to be the know-all and end-all of what is good and bad in the textile industry, but rather use it as a gentle guideline for your decision-making.

Substance Function Status Notes
Alum (Potassium Aluminum Sulfate) Mordant ✅ Approved Traditional mordant: safe, biodegradable, low toxicity
Aluminum Acetate Mordant ✅ Approved Especially useful for cellulose; less common, more costly
Aluminum Lactate Mordant ✅ Approved Biodegradable, used on cellulose and protein
Aluminum Triformate Mordant ✅ Approved Eco-alternative; low environmental toxicity
Tannins (e.g., oak galls, myrobalan) Mordant / assist ✅ Approved Natural mordant for cellulose; must be plant-derived
Ferrous Sulfate (Iron) Post-mordant / modifier ⚠️ Restricted use Allowed in very low concentrations (<6% WOF); must not exceed thresholds
Cream of Tartar (Potassium Bitartrate) Mordant assist ✅ Approved pH modifier with alum, helps clarity and brightness of shades
Citric Acid pH modifier ✅ Approved Aids in dye bath pH control; biodegradable
Tartaric Acid pH modifier ✅ Approved Similar use to citric acid
Sodium Carbonate (Soda Ash) Scouring / pH adjust ✅ Approved Common in cellulose scouring, indigo vats
Sodium Bicarbonate (Baking Soda) pH adjust ✅ Approved Gentle alkalizer, often used in protein fiber prep
Calcium Hydroxide (Slaked Lime) Indigo vat alkali ✅ Approved Traditional lime for fermentation vats
Ascorbic Acid (Vitamin C) Indigo vat reducer ✅ Approved Eco-alternative to chemical reducing agents
Fructose, Glucose, Molasses Indigo vat reducer ✅ Approved Used in fruit vats and eco-friendly reduction processes
Washing Soda (Sodium Carbonate) Scouring ✅ Approved Same as soda ash
Enzymes (e.g., pectinase, amylase) Scouring ✅ Approved Only microbial enzymes from non-GMO sources allowed

❌ Not GOTS-Approved (Prohibited or Highly Restricted)

Substance Reason for Exclusion
Copper Sulfate Heavy metal; toxic to aquatic life
Chrome Mordants (e.g., potassium dichromate) Carcinogenic, environmentally hazardous
Tin Compounds (e.g., Stannous Chloride) Not allowed under GOTS due to heavy metal content
Synthetic Fixatives or Retarders Usually petrochemical-based
EDTA, DTPA, and other chelating agents Poor biodegradability
Synthetic surfactants (non-GOTS listed) Many are non-biodegradable, may bioaccumulate
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3 comments

Thanks for this. Interesting and helpful. Dank je Suzanne

Marja van Nieuwenhuijzen

Great details. Thanks

Omila Bir

Great article – thanks for all the research.

Karen Selkl

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